Single-path supercontinuum laser spectroscopy combining MIR-ATR and NIR transmission
Publikation: Bidrag til bog/antologi/rapport › Konferencebidrag i proceedings › Forskning › fagfællebedømt
The strong absorption of water in the mid-infrared (MIR) causes difficulties in performing combined near-infrared (NIR) and MIR spectroscopy on aqueous samples using a single instrument. Combining spectra from different instruments can result in unwanted spectral variations, which can influence the prediction models and mitigate the advantages of the combination approaches. In this work, absorption spectra were collected in the NIR (1300nm-2500nm) and MIR (2500nm-3800nm) region by combining a single high-brightness broadband supercontinuum (SC) laser spanning from ∼1-4.0 μm with attenuated total reflectance (ATR) and a transmission cuvette in a single-path configuration to provide a uniform spectral response across the NIR and MIR regions. The measured NIR- and MIR- spectra were assessed based on their ability to predict varying concentrations of ethanol, sucrose, and L-proline in aqueous solutions. The NIR-based partial least square regression (PLSR) model gave higher prediction accuracy for sucrose (R2 = 0.95) as compared to both ethanol and L-proline (R2 = 0.75 and R2 = 0.57 respectively). On the other hand, the MIR-based model enhances the prediction accuracy of ethanol (R2 = 1.00) and L-proline (R2 = 0.62) while demonstrating no significant change in prediction accuracy for sucrose (R2 = 0.96). The prediction models based on the combined NIR-MIR spectra performed similar but slightly worse than the MIR-only models for ethanol and L-proline (R2 = 0.97 and R2 = 0.54 respectively), while for sucrose, it was slightly improved (R2 = 0.99).
Originalsprog | Engelsk |
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Titel | Terahertz, RF, Millimeter, and Submillimeter-Wave Technology and Applications XVII |
Redaktører | Laurence P. Sadwick, Tianxin Yang |
Antal sider | 5 |
Forlag | SPIE |
Publikationsdato | 2024 |
Artikelnummer | 1288508 |
ISBN (Elektronisk) | 9781510670303 |
DOI | |
Status | Udgivet - 2024 |
Begivenhed | Terahertz, RF, Millimeter, and Submillimeter-Wave Technology and Applications XVII 2024 - San Francisco, USA Varighed: 29 jan. 2024 → 1 feb. 2024 |
Konference
Konference | Terahertz, RF, Millimeter, and Submillimeter-Wave Technology and Applications XVII 2024 |
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Land | USA |
By | San Francisco |
Periode | 29/01/2024 → 01/02/2024 |
Sponsor | The Society of Photo-Optical Instrumentation Engineers (SPIE) |
Navn | Proceedings of SPIE - The International Society for Optical Engineering |
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Vol/bind | 12885 |
ISSN | 0277-786X |
Bibliografisk note
Funding Information:
The authors acknowledge the funding support from VILLUM FONDEN (Villum Investigator project Table-Top Synchrotons, No. 00037822) and The Danish Maritime Fund (2022-054). Disclosures: The authors declare there is no conflict of interest related to this manuscript.
Publisher Copyright:
© 2024 SPIE.
ID: 392990421